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Grades 9–12 · Materials & Matter

How does iron ore become steel?

Iron ore usually contains iron chemically bonded to oxygen in minerals such as iron oxides. Heating the ore until it melts is not enough to turn all that oxide into metal: the oxygen must be removed through chemical reduction. In a conventional blast-furnace route, carbon-based materials provide energy and generate reducing gases, including carbon monoxide.

P63 visual explanationOre-based ironmaking chemically removes oxygen from iron oxide. A representative carbon-monoxide reaction balances 1 Fe₂O₃ + 3 CO → 2 Fe + 3 CO₂. Iron atoms balance at 2 on each side, carbon at 3, and oxygen at 6. This net reaction is not a furnace recipe. The resulting carbon-rich iron must be refined: oxygen removes excess carbon and some other elements, then composition is adjusted for the chosen steel. Melting recycled steel in an electric furnace is another route. Temperatures, quantities and process controls are not provided.Ore reduction makes iron; refining makes steelOne ore-based route · recycled steel can follow an electric route1. Reduce oreIron oxide+ reducing gasIron + gas out2. Refine metalOxygen removesexcess carbonAdjust carbonand alloy content3. Cast steelThen shape it1 Fe₂O₃ + 3 CO → 2 Fe + 3 CO₂Representative reduction balance; not a furnace recipe.

In the diagramOre reduction makes iron; refining makes steelOne ore-based route · recycled steel can follow an electric route1. Reduce oreIron oxide+ reducing gasIron + gas out2. Refine metalOxygen removesexcess carbonAdjust carbonand alloy content3. Cast steelThen shape it1 Fe₂O₃ + 3 CO → 2 Fe + 3 CO₂Representative reduction balance; not a furnace recipe.

The ore-based route separates oxygen removal, composition refining and casting; the equation represents one reduction balance.

One representative overall reaction is Fe₂O₃ + 3CO → 2Fe + 3CO₂. Oxygen transfers from iron oxide to carbon monoxide, leaving metallic iron. Each element has the same number of atoms before and after the reaction. An actual furnace contains several linked reactions, and its iron product contains substantial dissolved carbon and other elements.

Steelmaking then changes that composition. In a basic oxygen furnace, oxygen reacts with excess carbon and some other elements in the molten iron. Carbon leaves largely in gases, while some other unwanted materials enter a separate slag. Refining and later additions set the remaining carbon and alloying elements for the intended steel. Steel is therefore not made merely by mixing carbon into an ore.

The liquid steel is cast into solid forms and then shaped by processes such as rolling. Another major route melts recycled steel in an electric arc furnace, often with additional metallic iron. That route starts with metal already separated from much of its original oxygen, although its composition still needs adjustment.

About this explanation

Starting knowledge: Understand chemical elements, oxides, balanced equations and the difference between a pure metal and an alloy.

Sources

  • World Steel Association — What is steel?
  • Environment and Climate Change Canada — Environmental Code of Practice for integrated steel mills: Section 2
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