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Mass spectrometry · 1877–1945

Francis William Aston

Aston began in fermentation chemistry, moved to work on discharge tubes, and joined Thomson at the Cavendish, where positive-ray analysis had suggested that neon might not be a single species. His response was to build a better instrument: a mass spectrograph whose electric and magnetic fields brought ions of the same mass-to-charge ratio to a focus regardless of their velocity spread, which is what made resolved isotopic lines possible.

Explore the supporting references at the foot of this article.

Contribution & context

From 1919 he used successive instruments to identify of most non-radioactive elements, formulated the whole-number rule, and measured the small departures from it that express nuclear binding energy. He received the 1922 Nobel Prize in Chemistry.

RSC Periodic Table — NeonLANL Periodic Table — NeonRSC Periodic Table — NeonLANL Periodic Table — Neon

Discoveries in context

Elements that arrive by decay ↗

Several elements were first found as short-lived members of radioactive series, and explaining them forced chemists to accept that one place in the table can hold atoms of different mass.

Sources & further reading

  1. RSC Periodic Table — Neon ↗Royal Society of ChemistryReference explanation · Source checked
  2. LANL Periodic Table — Neon ↗Los Alamos National LaboratoryReference explanation · Source checked
  3. RSC Periodic Table — Neon ↗Royal Society of ChemistryReference explanation · Source checked
  4. LANL Periodic Table — Neon ↗Los Alamos National LaboratoryReference explanation · Source checked

Sources and further reading. What the review labels mean