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Analytical chemistry and instrumentation · 1811–1899

Robert Wilhelm Bunsen

Bunsen’s reputation rests less on any theory than on instruments and methods that made other people’s work possible. At Heidelberg he developed a gas burner giving a hot, almost colourless flame — essential if the light from a sample is to be read rather than swamped — along with a carbon–zinc battery, an ice calorimeter and a grease-spot photometer. He lost the sight of one eye to an arsenic compound explosion early in his career and thereafter kept away from the organoarsenic work that had nearly killed him.

Explore the supporting references at the foot of this article.

Contribution & context

With Kirchhoff he established in 1859 that flame identify elements, and applied the method immediately: cesium in 1860 from evaporated water and rubidium in 1861 from lepidolite. Both were announced from their spectral lines before enough material existed to characterize them chemically.

NIST — CesiumUSGS — CesiumRSC Periodic Table — CesiumNIST — CesiumNIST — Cesium

Discoveries in context

Elements found by their colors ↗

Once a flame’s light could be spread into sharp lines and matched against a catalog, an element could be detected before anyone had a weighable sample of it.

Sources & further reading

  1. NIST — Cesium ↗National Institute of Standards and TechnologyReference explanation · Source checked
  2. USGS — Cesium ↗United States Geological SurveyReference explanation · Source checked
  3. RSC Periodic Table — Cesium ↗Royal Society of ChemistryReference explanation · Source checked
  4. NIST — Cesium ↗National Institute of Standards and TechnologyReference explanation · Source checked
  5. NIST — Cesium ↗National Institute of Standards and TechnologyReference explanation · Source checked

Sources and further reading. What the review labels mean