Industrial chemistry and saltpetre manufacture · 1777–1838
Bernard Courtois
Courtois inherited a saltpetre works and spent his career in the practical chemistry of nitrate production, which in Napoleonic France meant processing large quantities of seaweed ash for the potassium salts it contained. That industrial context is what put him in contact with concentrated marine residues; the discovery attributed to him is a manufacturing accident noticed by someone who knew what ought to have happened. He gained little financially from it and died in poverty.
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Contribution & context
In 1811, adding excess sulfuric acid to seaweed ash, he observed a violet vapor that condensed as dark . He recognized the substance as new and passed samples to others; Gay-Lussac and Davy established in 1813–1814 that it was an element analogous to chlorine, and it was named iodine for its color.
USGS — TinRSC Periodic Table — IodineUSGS — IodineRSC Periodic Table — PotassiumLANL Periodic Table — Potassium
Discoveries in context
A family that resists being isolated ↗
Chlorine, iodine, bromine and fluorine were all recognized in compounds long before they could be separated from them, and fluorine took more than a century.
Sources & further reading
- USGS — Tin ↗United States Geological SurveyReference explanation · Source checked
- RSC Periodic Table — Iodine ↗Royal Society of ChemistryReference explanation · Source checked
- USGS — Iodine ↗United States Geological SurveyReference explanation · Source checked
- RSC Periodic Table — Potassium ↗Royal Society of ChemistryReference explanation · Source checked
- LANL Periodic Table — Potassium ↗Los Alamos National LaboratoryReference explanation · Source checked
Sources and further reading. What the review labels mean